Contenu d'un ouvrage

Titre de l'ouvrage : The Organometallic Chemistry of the Transition Metals (R.B. Crabtree, 2014)

Num. Chap.	Titre du chapitre	Page
1	Introduction	1
2	Making Sense of Organometallic Complexes	40
3	Alkyls and Hydrides	69
4	Carbonyls, Phosphines, and Substitution	98
5	Pi-Complexes	134
6	Oxidative Addition and Reductive Elimination	163
7	Insertion and Elimination	185
8	Addition and Abstraction	204
9	Homogeneous Catalysis	224
10	Physical Methods	259
11	M–L Multiple Bonds	290
12	Applications	317
13	Clusters, Nanoparticles, Materials, and Surfaces	353
14	Organic Applications	383
15	Paramagnetic and High Oxidation-State Complexes	411
16	Bioorganometallic Chemistry	436

Chapitre 1 : Introduction	Page
Why Study Organometallic Chemistry?	1
Coordination Chemistry	3
Werner Complexes	4
The Trans Effect	9
Soft versus Hard Ligands	10
The Crystal Field	11
The Ligand Field	19
The sdⁿ Model and Hypervalency	21
Back Bonding	23
Electroneutrality	27
Types of Ligand	29