| Chapitre 1 : Equilibria and thermochemistry |
Page |
| Equilibrium-free enthalpy: reaction-free energy or Gibbs energy |
1 |
| Heat of reaction and variation of the entropy of reaction (reaction entropy) |
2 |
| Statistical thermodynamics |
4 |
| Standard heats of formation |
8 |
| What do standard heats of formation tell us about chemical bonding and ground-state properties of organic compounds? |
9 |
| Standard heats of typical organic reactions |
14 |
| Ionization energies and electron affinities |
20 |
| Homolytic bond dissociations; heats of formation of radicals |
22 |
| Heterolytic bond dissociation enthalpies |
28 |
| Electron transfer equilibria |
32 |
| Heats of formation of neutral, transient compounds |
32 |
| Electronegativity and absolute hardness |
37 |
| Chemical conversion and selectivity controlled by thermodynamics |
40 |
| Thermodynamic (equilibrium) isotopic effects |
49 |
