Contenu d'un ouvrage

Titre de l'ouvrage : Organometallic Chemistry and Catalysis (D. Astruc, 2007)

Num. Chap.	Titre du chapitre	Page
1	Monometallic transition-metal complexes	23
2	Bimetallic transition-metal complexes and clusters	47
3	Redox reactions, oxidative addition and σ-bond metathesis	81
4	Reactions of nucleophiles and electrophiles with complexes	109
5	Ligand substitution reactions	121
6	Insertion and extrusion reactions	135
7	Metal carbonyls and complexes of other monohapto L ligands	151
8	Metal-alkyl and -hydride complexes and other complexes of monohapto X ligands	175
9	Metal-carbene and -carbyne complexes and multiple bonds with transition metals	197
10	π complexes of mono- and polyenes and enyls	225
11	Metallocenes and sandwich complexes	251
12	Ionic and polar metal-carbon bonds: alkali and rare-earth complexes	289
13	Covalent chemistry of the organoelements of frontier (11, 12) and main (13-16) groups	313
14	Hydrogenation and hydroelementation of alkenes	357
15	Transformations of alkenes and alkynes	367
16	Oxidation of olefins	395
17	C-H activation and functionalization of alkanes and arenes	409
18	Carbonylation and carboxylation reactions	431
19	Bio-organometallic chemistry: enzymatic catalysis	441
20	Heterogeneous catalysis	457
21	Organometallic complexes in organic synthesis Examples of applications	489

Chapitre 1 : Monometallic transition-metal complexes	Page
The ligands	23
The characteristics of the transition-metal in the complexes	32
Hapticity of the ligands and linear writing of the complex formulas	36
The 18-electron rule: tendencies and exceptions	37
Bonding between the transition metal and the π-acceptor (CO, C₂H₄) and π-donor ligands (halogeno, alkoxy, amino)	41
Molecular orbital diagrams	44