| Chapitre 10 : Radical Reactions |
Page |
| Introduction: How Radicals Form and How They React |
449 |
| Homolytic Bond Dissociation Energies (ΔH°) |
451 |
| Reactions of Alkanes with Halogens |
454 |
| Chlorination of Methane: Mechanism of Reaction |
456 |
| Halogenation of Higher Alkanes |
459 |
| The Geometry of Alkyl Radicals |
462 |
| Reactions that Generate Tetrahedral Chirality Centers |
462 |
| Allylic Substitution and Allylic Radicals |
466 |
| Benzylic Substitution and Benzylic Radicals |
469 |
| Radical Addition to Alkenes: The Anti-Markovnikov Addition of Hydrogen Bromide |
472 |
| Radical Polymerization of Alkenes: Chain-Growth Polymers |
474 |
| Other Important Radical Reactions |
478 |