Contenu d'un ouvrage

Titre de l'ouvrage : Stereoelectronic Effects (V. Alabugin, 2016)

Num. Chap.	Titre du chapitre	Page
1	Introduction	1
2	Direct Effects of Orbital Overlap on Reactivity	8
3	Beyond Orbital Overlap: Additional Factors Important for Orbital Interactions. Classifying Delocalizing Interactions	42
4	Computational and Theoretical Approaches for Studies of Stereoelectronic Effects	54
5	General Stereoelectronic Trends – Donors, Acceptors, and Chameleons	62
6	Stereoelectronic Effects with Donor and Acceptor Separated by a Single Bond Bridge: The Broad Spectrum of Orbital Contributions to Conformational Analysis	97
7	Stereoelectronic Effects with Donor and Acceptor Separated by a Vinyl Bridge	183
8	Remote Stereoelectronic Effects	214
9	Transition State Stabilization with Stereoelectronic Effects: Stereoelectronic Control of Reaction Bottlenecks	236
10	Stereoelectronic Effects in Reaction Design	257
11	Stereoelectronic Effects in Action: The Many Doors Opened by Orbital Interactions	275
12	Probing Stereoelectronic Effects with Spectroscopic Methods	322

Chapitre 11 : Stereoelectronic Effects in Action: The Many Doors Opened by Orbital Interactions	Page
Gauche effect (σ ➔ σ* interactions)	275
Trans-effect – the cousin of gauche effect in organometallic chemistry	283
Anomeric effects (n ➔ σ* interactions)	284
Bioorganic chemistry and enzyme reactions	311