Agrégation chimie Montrouge

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Titre de l'ouvrage : Organometallic Chemistry and Catalysis (D. Astruc, 2007)

Table des chapitres

 Num. Chap.  Titre du chapitre  Page 
1  Monometallic transition-metal complexes  23
2  Bimetallic transition-metal complexes and clusters  47
3  Redox reactions, oxidative addition and σ-bond metathesis  81
4  Reactions of nucleophiles and electrophiles with complexes  109
5  Ligand substitution reactions  121
6  Insertion and extrusion reactions  135
7  Metal carbonyls and complexes of other monohapto L ligands  151
8  Metal-alkyl and -hydride complexes and other complexes of monohapto X ligands  175
9  Metal-carbene and -carbyne complexes and multiple bonds with transition metals  197
10  π complexes of mono- and polyenes and enyls  225
11  Metallocenes and sandwich complexes  251
12  Ionic and polar metal-carbon bonds: alkali and rare-earth complexes  289
13  Covalent chemistry of the organoelements of frontier (11, 12) and main (13-16) groups  313
14  Hydrogenation and hydroelementation of alkenes  357
15  Transformations of alkenes and alkynes  367
16  Oxidation of olefins  395
17  C-H activation and functionalization of alkanes and arenes  409
18  Carbonylation and carboxylation reactions  431
19  Bio-organometallic chemistry: enzymatic catalysis  441
20  Heterogeneous catalysis  457
21  Organometallic complexes in organic synthesis Examples of applications  489
 
 Chapitre 11 : Metallocenes and sandwich complexes   Page 
 Structure of the metallocenes  251
 Redox properties of the sandwich metallocenes  255
 Metallocene synthesis  256
 Chemical properties of metallocenes  258
 Triple- and multiple-decker sandwich complexes  266
 Non-sandwich metallocenes derivatives  268
 Metal-bis-arene sandwich complexes  270
 Cyclopentadienyl-metal-arene complexes  274
Dernière mise à jour : le 5 juin 2025     home