Contenu d'un ouvrage

Titre de l'ouvrage : Intermolecular and Surface Forces (J. Israelachvili, 2011)

Num. Chap.	Titre du chapitre	Page
1	Historical Perspective	3
2	Thermodynamic and Statistical Aspects of Intermolecular Forces	23
3	Strong Intermolecular Forces: Covalent and Coulomb Interactions	53
4	Interactions Involving Polar Molecules	71
5	Interactions Involving the Polarization of Molecules	91
6	Van der Waals Forces	107
7	Repulsive Steric Forces, Total Intermolecular Pair Potentials, and Liquid Structure	133
8	Special Interactions: Hydrogen-Bonding and Hydrophobic and Hydrophilic Interactions	151
9	Nonequilibrium and Time-Dependent Interactions	169
10	Unifying Concepts in Intermolecular and Interparticle Forces	191
11	Contrasts between Intermolecular, Interparticle, and Intersurface Forces	205
12	Force-Measuring Techniques	223
13	Van der Waals Forces between Particles and Surfaces	253
14	Electrostatic Forces between Surfaces in Liquids	291
15	Solvation, Structural, and Hydration Forces	341
16	Steric (Polymer-Mediated) and Thermal Fluctuation Forces	381
17	Adhesion and Wetting Phenomena	415
18	Friction and Lubrication Forces	469
19	Thermodynamic Principles of Self-Assembly	503
20	Soft and Biological Structures	535
21	Interactions of Biological Membranes and Structures	577
22	Dynamic Biointeractions	617

Chapitre 14 : Electrostatic Forces between Surfaces in Liquids	Page
The Charging of Surfaces in Liquids: the Electric “Double-Layer”	291
Charged Surfaces in Water: No Added Electrolyte - “Counterions Only”	293
The Poisson-Boltzmann (PB) Equation	293
Surface Charge, Electric Field, and Counterion Concentration at a Surface: “Contact” Values	294
Counterion Concentration Profile Away from a Surface	296
Origin of the Ionic Distribution, Electric Field, Surface Potential, and Pressure	298
The Pressure between Two Charged Surfaces in Water: the Contact Value Theorem	300
Limit of Large Separations: Thick Wetting Films	303
Limit of Small Separations: Osmotic Limit and Charge Regulation	305
Charged Surfaces in Electrolyte Solutions	306
The Grahame Equation	308
Surface Charge and Potential of Isolated Surfaces	309
Effect of Divalent Ions	311
The Debye Length	312
Variation of Potential ψ_x and Ionic Concentrations ρ_x Away from a Surface	313
Electrostatic Double-Layer Interaction Forces and Energies between Various Particle Surfaces	314
Exact Solutions for Constant Charge and Constant Potential Interactions: Charge Regulation	318
Asymmetric Surfaces	321
Ion-Condensation and Ion-Correlation Forces	322
More Complex Systems: Finite Reservoir Systems and Finite Ion-Size Effects	325
Van der Waals and Double-Layer Forces Acting Together: the DLVO Theory	326
Experimental Measurements of Double-Layer and DLVO Forces	331
Electrokinetic Forces	334
Discrete Surface Charges and Dipoles	335