Contenu d'un ouvrage

Titre de l'ouvrage : Chemical Thermodynamics (I.M. Klotz, R.M. Rosenberg, 2000)

Num. Chap.	Titre du chapitre	Page
1	Introduction	1
2	Mathematical Preparation for Thermodynamics	9
3	The First Law of Thermodynamics	29
4	Enthalpy, Enthalpy of Reaction, and Heat Capacity	43
5	Applications of the First Law to Gases	81
6	The Second Law of Thermodynamics	111
7	Equilibrium and Spontaneity for Systems at Constant Temperature	159
8	Application of the Gibbs Function and the Planck Function to Some Phase Changes	193
9	Thermodynamics of Systems of Variable Composition	211
10	Mixtures of Gases and Equilibrium in Gaseous Mixtures	227
11	The Third Law of Thermodynamics	259
12	Application of the Gibbs Function to Chemical Changes	281
13	The Phase Rule	303
14	The Ideal Solution	319
15	Dilute Solutions of Nonelectrolytes	337
16	Activities, Excess Gibbs Functions, and Standard States for Nonelectrolytes	357
17	Determination of Nonelectrolyte Activities and Excess Gibbs Functions from Experimental Data	385
18	Calculation of Partial Molar Quantities and Excess Molar Quantities from Experimental Data: Volume and Enthalpy	407
19	Activity, Activity Coefficients, and Osmotic Coefficients of Strong Electrolytes	439
20	Changes in Gibbs Function for Processes in Solutions	471
21	Systems Subject to a Gravitational or a Centrifugal Field	499
22	Estimation of Thermodynamic Quantities	511

Chapitre 16 : Activities, Excess Gibbs Functions, and Standard States for Nonelectrolytes	Page
Definitions of Activities and Activity Coefficients	358
Choice of Standard States	359
Gibbs Function and the Equilibrium Constant in Terms of Activity	365
Dependence of Activity on Pressure	367
Dependence of Activity on Temperature	368
Standard Entropy	370
Deviations from Ideality in Terms of Excess Thermodynamic Functions	373
Regular Solutions and Henry's Law	376
Regular Solutions and Limited Miscibility	378