| Chapitre 17 : Reactions at the α-Carbon |
Page |
| The Acidity of an α-Hydrogen |
802 |
| Keto–Enol Tautomers |
805 |
| Keto–Enol Interconversion |
806 |
| Halogenation of the α-Carbon of Aldehydes and Ketones |
807 |
| Halogenation of the α-Carbon of Carboxylic Acids |
809 |
| Forming an Enolate Ion |
810 |
| Alkylating the α-Carbon |
811 |
| Alkylating and Acylating the α-Carbon Via an Enamine Intermediate |
814 |
| Alkylating the β-Carbon |
815 |
| An Aldol Addition Forms α,β-Hydroxyaldehyde or α,β-Hydroxyketone |
817 |
| The Dehydration of Aldol Addition Products Forms α,β-Unsaturated Aldehydes and Ketones |
819 |
| A Crossed Aldol Addition |
821 |
| A Claisen Condensation Forms α,β-Keto Ester |
824 |
| Other Crossed Condensations |
827 |
| Intramolecular Condensations and Intramolecular Aldol Additions |
827 |
| The Robinson Annulation |
830 |
| CO2 Can be Removed from a Carboxylic Acid that has a Carbonyl Group at the 3-Position |
831 |
| The Malonic Ester Synthesis: A Way to Synthesize a Carboxylic Acid |
833 |
| The Acetoacetic Ester Synthesis: A Way to Synthesize a Methyl Ketone |
834 |
| Making New Carbon–Carbon Bonds |
836 |
| Reactions at the α-Carbon in Living Systems |
838 |