Agrégation chimie Montrouge

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Titre de l'ouvrage : Organic Chemistry (P.Y. Bruice, 2015)

Table des chapitres

 Num. Chap.  Titre du chapitre  Page 
1  Remembering General Chemistry: Electronic Structure and Bonding  2
2  Acids and Bases: Central to Understanding Organic Chemistry  50
3  An Introduction to Organic Compounds: Nomenclature, Physical Properties, and Structure  88
4  Isomers: The Arrangement of Atoms in Space  143
5  Alkenes: Structure, Nomenclature, and an Introduction to Reactivity. Thermodynamics and Kinetics  190
6  The Reactions of Alkenes. The Stereochemistry of Addition Reactions  235
7  The Reactions of Alkynes. An Introduction to Multistep Synthesis  288
8  Delocalized Electrons: Their Effect on Stability, pKA, and the Products of a Reaction. Aromaticity and Electronic Effects: An Introduction to the Reactions of Benzene  318
9  Substitution and Elimination Reactions  391
10  Reactions of Alcohols, Ethers, Epoxides, Amines, and Sulfur-Containing Compounds  458
11  Organometallic Compounds  508
12  Radicals  532
13  Mass Spectrometry; Infrared Spectroscopy; UV/Vis Spectroscopy  567
14  NMR Spectroscopy  620
15  Reactions of Carboxylic Acids and Carboxylic Acid Derivatives  686
16  Reactions of Aldehydes and Ketones. More Reactions of Carboxylic Acid Derivatives  739
17  Reactions at the α-Carbon  801
18  Reactions of Benzene and Substituted Benzenes  868
19  More About Amines. Reactions of Heterocyclic Compounds  924
20  The Organic Chemistry of Carbohydrates  950
21  Amino Acids, Peptides, and Proteins  986
22  Catalysis in Organic Reactions and in Enzymatic Reactions  1030
23  The Organic Chemistry of the Coenzymes, Compounds Derived from Vitamins  1063
24  The Organic Chemistry of the Metabolic Pathways  1099
25  The Organic Chemistry of Lipids  1127
26  The Chemistry of the Nucleic Acids  1155
27  Synthetic Polymers  1182
28  Pericyclic Reactions  1212
 
 Chapitre 17 : Reactions at the α-Carbon   Page 
 The Acidity of an α-Hydrogen  802
 Keto–Enol Tautomers  805
 Keto–Enol Interconversion  806
 Halogenation of the α-Carbon of Aldehydes and Ketones  807
 Halogenation of the α-Carbon of Carboxylic Acids  809
 Forming an Enolate Ion  810
 Alkylating the α-Carbon  811
 Alkylating and Acylating the α-Carbon Via an Enamine Intermediate  814
 Alkylating the β-Carbon  815
 An Aldol Addition Forms α,β-Hydroxyaldehyde or α,β-Hydroxyketone  817
 The Dehydration of Aldol Addition Products Forms α,β-Unsaturated Aldehydes and Ketones  819
 A Crossed Aldol Addition  821
 A Claisen Condensation Forms α,β-Keto Ester  824
 Other Crossed Condensations  827
 Intramolecular Condensations and Intramolecular Aldol Additions  827
 The Robinson Annulation  830
 CO2 Can be Removed from a Carboxylic Acid that has a Carbonyl Group at the 3-Position  831
 The Malonic Ester Synthesis: A Way to Synthesize a Carboxylic Acid  833
 The Acetoacetic Ester Synthesis: A Way to Synthesize a Methyl Ketone  834
 Making New Carbon–Carbon Bonds  836
 Reactions at the α-Carbon in Living Systems  838
Dernière mise à jour : le 5 juin 2025     home