Agrégation chimie Montrouge

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Titre de l'ouvrage : Intermolecular and Surface Forces (J. Israelachvili, 2011)

Table des chapitres

 Num. Chap.  Titre du chapitre  Page 
1  Historical Perspective  3
2  Thermodynamic and Statistical Aspects of Intermolecular Forces  23
3  Strong Intermolecular Forces: Covalent and Coulomb Interactions  53
4  Interactions Involving Polar Molecules  71
5  Interactions Involving the Polarization of Molecules  91
6  Van der Waals Forces  107
7  Repulsive Steric Forces, Total Intermolecular Pair Potentials, and Liquid Structure  133
8  Special Interactions: Hydrogen-Bonding and Hydrophobic and Hydrophilic Interactions  151
9  Nonequilibrium and Time-Dependent Interactions  169
10  Unifying Concepts in Intermolecular and Interparticle Forces  191
11  Contrasts between Intermolecular, Interparticle, and Intersurface Forces  205
12  Force-Measuring Techniques  223
13  Van der Waals Forces between Particles and Surfaces  253
14  Electrostatic Forces between Surfaces in Liquids  291
15  Solvation, Structural, and Hydration Forces  341
16  Steric (Polymer-Mediated) and Thermal Fluctuation Forces  381
17  Adhesion and Wetting Phenomena  415
18  Friction and Lubrication Forces  469
19  Thermodynamic Principles of Self-Assembly  503
20  Soft and Biological Structures  535
21  Interactions of Biological Membranes and Structures  577
22  Dynamic Biointeractions  617
 
 Chapitre 19 : Thermodynamic Principles of Self-Assembly   Page 
 Introduction: Soft Structures  503
 Fundamental Thermodynamic Equations of Self-Assembly  504
 Conditions Necessary for the Formation of Aggregates  509
 Effect of Dimensionality and Geometry: Rods, Discs, and Spheres  510
 The Critical Micelle Concentration (CMC)  512
 Infinite Aggregates (Phase Separation) versus Finite Sized Aggregates (Micellization)  513
 Hydrophobic Energy of Transfer  514
 Nucleation and Growth of Aggregates  515
 2D Structures on Surfaces: Soluble and Insoluble Monolayers  520
 Line Tension and 2D Micelles (Domains)  521
 Soluble Monolayers and the Gibbs Adsorption Isotherm  524
 Size Distributions of Self-Assembled Structures  524
 Large and More Complex Amphiphilic Structures  527
 Effects of Interactions between Aggregates: Mesophases and Multilayers  528
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