| Chapitre 19 : Thermodynamic Principles of Self-Assembly |
Page |
| Introduction: Soft Structures |
503 |
| Fundamental Thermodynamic Equations of Self-Assembly |
504 |
| Conditions Necessary for the Formation of Aggregates |
509 |
| Effect of Dimensionality and Geometry: Rods, Discs, and Spheres |
510 |
| The Critical Micelle Concentration (CMC) |
512 |
| Infinite Aggregates (Phase Separation) versus Finite Sized Aggregates (Micellization) |
513 |
| Hydrophobic Energy of Transfer |
514 |
| Nucleation and Growth of Aggregates |
515 |
| 2D Structures on Surfaces: Soluble and Insoluble Monolayers |
520 |
| Line Tension and 2D Micelles (Domains) |
521 |
| Soluble Monolayers and the Gibbs Adsorption Isotherm |
524 |
| Size Distributions of Self-Assembled Structures |
524 |
| Large and More Complex Amphiphilic Structures |
527 |
| Effects of Interactions between Aggregates: Mesophases and Multilayers |
528 |