| Chapitre 2 : Additivity rules for thermodynamic parameters and deviations |
Page |
| Molecular groups |
110 |
| Determination of the standard group equivalents (group equivalents) |
111 |
| Determination of standard entropy increments |
113 |
| Steric effects |
114 |
| Ring strain and conformational flexibility of cyclic compounds |
117 |
| π/π*, n/π*, σ/π*, and n/σ* interactions |
127 |
| Other deviations to additivity rules |
144 |
| Major role of translational entropy on equilibria |
146 |
| Entropy of cyclization: loss of degrees of free rotation |
151 |
| Entropy as a synthetic tool |
151 |
