Contenu d'un ouvrage

Titre de l'ouvrage : Organometallic Chemistry and Catalysis (D. Astruc, 2007)

Num. Chap.	Titre du chapitre	Page
1	Monometallic transition-metal complexes	23
2	Bimetallic transition-metal complexes and clusters	47
3	Redox reactions, oxidative addition and σ-bond metathesis	81
4	Reactions of nucleophiles and electrophiles with complexes	109
5	Ligand substitution reactions	121
6	Insertion and extrusion reactions	135
7	Metal carbonyls and complexes of other monohapto L ligands	151
8	Metal-alkyl and -hydride complexes and other complexes of monohapto X ligands	175
9	Metal-carbene and -carbyne complexes and multiple bonds with transition metals	197
10	π complexes of mono- and polyenes and enyls	225
11	Metallocenes and sandwich complexes	251
12	Ionic and polar metal-carbon bonds: alkali and rare-earth complexes	289
13	Covalent chemistry of the organoelements of frontier (11, 12) and main (13-16) groups	313
14	Hydrogenation and hydroelementation of alkenes	357
15	Transformations of alkenes and alkynes	367
16	Oxidation of olefins	395
17	C-H activation and functionalization of alkanes and arenes	409
18	Carbonylation and carboxylation reactions	431
19	Bio-organometallic chemistry: enzymatic catalysis	441
20	Heterogeneous catalysis	457
21	Organometallic complexes in organic synthesis Examples of applications	489

Chapitre 21 : Organometallic complexes in organic synthesis Examples of applications	Page
Protection and stabilization of unsaturated organic derivatives and fragments	489
Nucleophilic and electrophilic reactions on hydrocarbon ligands	492
General methods of C-C bond formation using the oxidative addition of an organic halide or a related electrophile	497
Extension of palladium catalysis to the formation of C-O and C-N bonds	516
Oxidative coupling reactions of alkynes with other unsaturated fragments for the formation of cyclic and heterocyclic compounds	518
Metal-carbene complexes in organic synthesis	521
Examples of asymmetric catalysis	523