| Chapitre 22 : d-Metal organometallic chemistry |
Page |
| Stable electron configurations |
580 |
| Electron-count preference |
581 |
| Electron counting and oxidation states |
582 |
| Nomenclature |
584 |
| Carbon monoxide |
585 |
| Phosphines |
587 |
| Hydrides and dihydrogen complexes |
588 |
| η1-Alkyl, -alkenyl, -alkynyl, and -aryl ligands |
589 |
| η2-Alkene and -alkyne ligands |
590 |
| Nonconjugated diene and polyene ligands |
591 |
| Butadiene, cyclobutadiene, and cyclooctatetraene |
591 |
| Benzene and other arenes |
593 |
| The allyl ligand |
594 |
| Cyclopentadiene and cycloheptatriene |
595 |
| Carbenes |
597 |
| Alkanes, agostic hydrogens, and noble gases |
597 |
| Dinitrogen and nitrogen monoxide |
598 |
| d-Block carbonyls |
599 |
| Metallocenes |
606 |
| Metal–metal bonding and metal clusters |
610 |
| Ligandsubstitution |
614 |
| Oxidative addition and reductive elimination |
617 |
| σ-Bond metathesis |
619 |
| 1,1-Migratory insertion reactions |
619 |
| 1,2-Insertions and β-hydride elimination |
620 |
| α-, γ-, and δ-Hydride eliminations and cyclometallations |
621 |