Chapitre 22 : d-Metal organometallic chemistry |
Page |
Stable electron configurations |
580 |
Electron-count preference |
581 |
Electron counting and oxidation states |
582 |
Nomenclature |
584 |
Carbon monoxide |
585 |
Phosphines |
587 |
Hydrides and dihydrogen complexes |
588 |
η1-Alkyl, -alkenyl, -alkynyl, and -aryl ligands |
589 |
η2-Alkene and -alkyne ligands |
590 |
Nonconjugated diene and polyene ligands |
591 |
Butadiene, cyclobutadiene, and cyclooctatetraene |
591 |
Benzene and other arenes |
593 |
The allyl ligand |
594 |
Cyclopentadiene and cycloheptatriene |
595 |
Carbenes |
597 |
Alkanes, agostic hydrogens, and noble gases |
597 |
Dinitrogen and nitrogen monoxide |
598 |
d-Block carbonyls |
599 |
Metallocenes |
606 |
Metal–metal bonding and metal clusters |
610 |
Ligandsubstitution |
614 |
Oxidative addition and reductive elimination |
617 |
σ-Bond metathesis |
619 |
1,1-Migratory insertion reactions |
619 |
1,2-Insertions and β-hydride elimination |
620 |
α-, γ-, and δ-Hydride eliminations and cyclometallations |
621 |