| Chapitre 3 : The Kinetic Analysis of Experimental Data |
Page |
| The Experimental Data |
44 |
| Dependence of Rate on Concentration |
47 |
| Meaning of the Rate Expression |
48 |
| Units of the Rate Constant, k |
49 |
| The Significance of the Rate Constant as Opposed to the Rate |
50 |
| Determining the Order and Rate Constant from Experimental Data |
52 |
| Systematic Ways of Finding the Order and Rate Constant from Rate/Concentration Data |
53 |
| Drawbacks of the Rate/Concentration Methods of Analysis |
58 |
| Integrated Rate Expressions |
58 |
| First Order Reactions |
62 |
| Second Order Reactions |
66 |
| Zero Order Reaction |
68 |
| Integrated Rate Expressions for Other Orders |
71 |
| Main Features of Integrated Rate Equations |
71 |
| Pseudo-order Reactions |
74 |
| Determination of the Product Concentration at Various Times |
77 |
| Expressing the Rate in Terms of Reactants or Products for Non-simple Stoichiometry |
79 |
| The Kinetic Analysis for Complex Reactions |
79 |
| The Steady State Assumption |
84 |
| General Treatment for Solving Steady States |
86 |
| Reversible Reactions |
89 |
| Pre-equilibria |
92 |
| Dependence of Rate on Temperature |
92 |
