Agrégation chimie Montrouge

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Titre de l'ouvrage : Thermodynamics of Molecular Species (E. Grünwald, 1997)

Table des chapitres

 Num. Chap.  Titre du chapitre  Page 
1  Thermodynamic Components and Molecular Species  1
2  Gibbs Free Energy, Chemical Equilibrium, and Correspondence Theorems  17
3  Dilute Solutions, Standard Partial Free Energies, and the Stability Theorem  43
4  Displacements from Equilibrium and Error Tolerance  78
5  Linear Free-Energy Relationships, Transition-State Theory, and Error Tolerance  94
6  Enthalpy—Entropy Compensation and Dormant Interactions  120
7  Effect of Molar Shifts on State Functions  137
8  Molar-Shift Terms in Dilute Solutions  157
9  Hard-Sphere and Potential-Energy Cages Around Molecules in Liquids  187
10  Environmental Isomers, Molecular Complexes, and Cage Exchange in Liquids  217
11  Solvation in Dilute Solutions  237
12  Thermodynamics of Ionic Species  259
 
 Chapitre 3 : Dilute Solutions, Standard Partial Free Energies, and the Stability Theorem   Page 
 Partial Free Energy in Ideal-Gas Mixtures  43
 Dilute Liquid Solutions: Henry's Law  45
 Units and Standard States  49
 Equilibrium Constants in Dilute Solutions  54
 The Solvent in Dilute Solutions  55
 Solute-Induced Medium Effects  59
 Two-Component Solvents  65
 Stability Theorem  72
 Statistical Form of the Stability Theorem  73
Dernière mise à jour : le 5 juin 2025     home