Agrégation chimie Montrouge

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Titre de l'ouvrage : Organic Mechanisms (R. Brückner, M. Harmata, 2010)

Table des chapitres

 Num. Chap.  Titre du chapitre  Page 
1  Radical Substitution Reactions at the Saturated C Atom  1
2  Nucleophilic Substitution Reactions at the Saturated C Atom  53
3  Electrophilic Additions to the C=C Double Bond  103
4  β-Eliminations  157
5  Substitution Reactions on Aromatic Compounds  201
6  Nucleophilic Substitution Reactions at the Carboxyl Carbon  259
7  Carboxylic Compounds, Nitriles, and Their Interconversion  321
8  Carbonic Acid Derivatives and Heterocumulenes and Their Interconversion  339
9  Additions of Heteroatom Nucleophiles to Carbonyl Compounds and Subsequent Reactions-Condensations of Heteroatom Nucleophiles with Carbonyl Compounds  359
10  Addition of Hydride Donors and of Organometallic Compounds to CarbonylCompounds  397
11  Conversion of Phosphorus- or Sulfur-Stabilized C Nucleophiles with Carbonyl Compounds: Addition-Induced Condensations  457
12  The Chemistry of Enols and Enamines  487
13  Chemistry of the Alkaline Earth Metal Enolates  519
14  Rearrangements  595
15  Thermal Cycloadditions  643
16  Transition Metal-Mediated Alkenylations, Arylations, and Alkynylations  691
17  Oxidations and Reductions  737
 
 Chapitre 4 : β-Eliminations   Page 
 Concepts of Elimination Reactions  157
 β-Eliminations of H/Het via Cyclic Transition States  164
 β-Eliminations of H/Het via Acyclic Transition States: The Mechanistic Alternatives  167
 E2 Eliminations of H/Het and the E2/SN2 Competition  168
 E1 Elimination of H/Het from Rtert-X and the E1/SN1 Competition  179
 E1cb Eliminations  189
 β-Eliminations of Het1/Het2  194
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