Contenu d'un ouvrage

Titre de l'ouvrage : Physical Organic Chemistry (N.S. Isaacs, 1995)

Num. Chap.	Titre du chapitre	Page
1	Models of chemical bonding	1
2	Kinetics and thermodynamics	87
3	Reagents and reaction mechanisms	129
4	Correlation of structure with reactivity	146
5	Solvent effects	193
6	Acids and bases, electrophiles and nucleophiles	235
7	Kinetic isotope effects	287
8	Steric and conformational properties	319
9	Homogeneous catalysis	369
10	Substitution reactions at carbon	418
11	Elimination reactions	551
12	Polar addition reactions	599
13	Intramolecular reactions	643
14	Pericyclic reactions	701
15	Reactions via free radicals	767
16	Organic photochemistry	837

Chapitre 4 : Correlation of structure with reactivity	Page
Electronic demands	146
The Hammett equation	149
Substituent constants σ	151
Theories of substituent effects	151
Interpretation of σ-values	156
Reaction constants, ρ	161
Deviations from the Hammett equation	161
Dual-parameter correlations: the flowering of LFER	170
Molecular orbital considerations	183
Cross-interaction terms	186