Agrégation chimie Montrouge

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Titre de l'ouvrage : Thermodynamics of Molecular Species (E. Grünwald, 1997)

Table des chapitres

 Num. Chap.  Titre du chapitre  Page 
1  Thermodynamic Components and Molecular Species  1
2  Gibbs Free Energy, Chemical Equilibrium, and Correspondence Theorems  17
3  Dilute Solutions, Standard Partial Free Energies, and the Stability Theorem  43
4  Displacements from Equilibrium and Error Tolerance  78
5  Linear Free-Energy Relationships, Transition-State Theory, and Error Tolerance  94
6  Enthalpy—Entropy Compensation and Dormant Interactions  120
7  Effect of Molar Shifts on State Functions  137
8  Molar-Shift Terms in Dilute Solutions  157
9  Hard-Sphere and Potential-Energy Cages Around Molecules in Liquids  187
10  Environmental Isomers, Molecular Complexes, and Cage Exchange in Liquids  217
11  Solvation in Dilute Solutions  237
12  Thermodynamics of Ionic Species  259
 
 Chapitre 5 : Linear Free-Energy Relationships, Transition-State Theory, and Error Tolerance   Page 
 Reaction Series and Free-Energy Perturbations  95
 Linear Free-Energy Plots Involving Rate Constants  98
 Transition-State Theory  105
 Thermodynamic Properties of Transition States  114
 Error Tolerance in Free-Energy Relationships  115
Dernière mise à jour : le 5 juin 2025     home