Agrégation chimie Montrouge

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Titre de l'ouvrage : Stereoelectronic Effects (V. Alabugin, 2016)

Table des chapitres

 Num. Chap.  Titre du chapitre  Page 
1  Introduction  1
2  Direct Effects of Orbital Overlap on Reactivity  8
3  Beyond Orbital Overlap: Additional Factors Important for Orbital Interactions. Classifying Delocalizing Interactions  42
4  Computational and Theoretical Approaches for Studies of Stereoelectronic Effects  54
5  General Stereoelectronic Trends – Donors, Acceptors, and Chameleons  62
6  Stereoelectronic Effects with Donor and Acceptor Separated by a Single Bond Bridge: The Broad Spectrum of Orbital Contributions to Conformational Analysis  97
7  Stereoelectronic Effects with Donor and Acceptor Separated by a Vinyl Bridge  183
8  Remote Stereoelectronic Effects  214
9  Transition State Stabilization with Stereoelectronic Effects: Stereoelectronic Control of Reaction Bottlenecks  236
10  Stereoelectronic Effects in Reaction Design  257
11  Stereoelectronic Effects in Action: The Many Doors Opened by Orbital Interactions  275
12  Probing Stereoelectronic Effects with Spectroscopic Methods  322
 
 Chapitre 5 : General Stereoelectronic Trends – Donors, Acceptors, and Chameleons   Page 
 Three types of delocalization: conjugation, hyperconjugation, and σ-conjugation  62
 Geminal and vicinal interactions  63
 Stereoelectronic main rule: antiperiplanarity  64
 Scales of donor and acceptor ability of orbitals: polarization, hybridization, and orbital energy effects  68
 Cooperativity of stereoelectronic effects and antiperiplanar lone pair hypothesis (ALPH) theory – several donors working together  91
Dernière mise à jour : le 5 juin 2025     home