Contenu d'un ouvrage

Titre de l'ouvrage : Chemical Thermodynamics (I.M. Klotz, R.M. Rosenberg, 2000)

Num. Chap.	Titre du chapitre	Page
1	Introduction	1
2	Mathematical Preparation for Thermodynamics	9
3	The First Law of Thermodynamics	29
4	Enthalpy, Enthalpy of Reaction, and Heat Capacity	43
5	Applications of the First Law to Gases	81
6	The Second Law of Thermodynamics	111
7	Equilibrium and Spontaneity for Systems at Constant Temperature	159
8	Application of the Gibbs Function and the Planck Function to Some Phase Changes	193
9	Thermodynamics of Systems of Variable Composition	211
10	Mixtures of Gases and Equilibrium in Gaseous Mixtures	227
11	The Third Law of Thermodynamics	259
12	Application of the Gibbs Function to Chemical Changes	281
13	The Phase Rule	303
14	The Ideal Solution	319
15	Dilute Solutions of Nonelectrolytes	337
16	Activities, Excess Gibbs Functions, and Standard States for Nonelectrolytes	357
17	Determination of Nonelectrolyte Activities and Excess Gibbs Functions from Experimental Data	385
18	Calculation of Partial Molar Quantities and Excess Molar Quantities from Experimental Data: Volume and Enthalpy	407
19	Activity, Activity Coefficients, and Osmotic Coefficients of Strong Electrolytes	439
20	Changes in Gibbs Function for Processes in Solutions	471
21	Systems Subject to a Gravitational or a Centrifugal Field	499
22	Estimation of Thermodynamic Quantities	511

Chapitre 6 : The Second Law of Thermodynamics	Page
The Need for a Second Law	111
The Nature of the Second Law	112
The Carnot Cycle	113
The Thermodynamic Temperature Scale	120
The Definition of S, the Entropy of a System	125
The Proof that S is a Thermodynamic Property	126
Entropy Changes in Reversible Processes	130
Entropy Changes in Irreversible Processes	133
General Equations for the Entropy of Gases	142
Temperature–Entropy Diagram	144
Entropy as an Index of Exhaustion	146