Agrégation chimie Montrouge

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Titre de l'ouvrage : Thermodynamics of Molecular Species (E. Grünwald, 1997)

Table des chapitres

 Num. Chap.  Titre du chapitre  Page 
1  Thermodynamic Components and Molecular Species  1
2  Gibbs Free Energy, Chemical Equilibrium, and Correspondence Theorems  17
3  Dilute Solutions, Standard Partial Free Energies, and the Stability Theorem  43
4  Displacements from Equilibrium and Error Tolerance  78
5  Linear Free-Energy Relationships, Transition-State Theory, and Error Tolerance  94
6  Enthalpy—Entropy Compensation and Dormant Interactions  120
7  Effect of Molar Shifts on State Functions  137
8  Molar-Shift Terms in Dilute Solutions  157
9  Hard-Sphere and Potential-Energy Cages Around Molecules in Liquids  187
10  Environmental Isomers, Molecular Complexes, and Cage Exchange in Liquids  217
11  Solvation in Dilute Solutions  237
12  Thermodynamics of Ionic Species  259
 
 Chapitre 8 : Molar-Shift Terms in Dilute Solutions   Page 
 A Renewed Look at the Dilute-Solution Model  158
 Molar-Shift Terms Based on the Law of Mass Action  162
 Solute-Induced Molar Shifts in the Solvent  167
 Water and Nonpolar Solutes  173
 Alcohols and Alcohol—Water Solvents  182
Dernière mise à jour : le 5 juin 2025     home