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Titre de l'ouvrage : Organic Chemistry (P.Y. Bruice, 2015)

Table des chapitres

Num. Chap.  Titre du chapitre  Page  1  Remembering General Chemistry: Electronic Structure and Bonding  2 2  Acids and Bases: Central to Understanding Organic Chemistry  50 3  An Introduction to Organic Compounds: Nomenclature, Physical Properties, and Structure  88 4  Isomers: The Arrangement of Atoms in Space  143 5  Alkenes: Structure, Nomenclature, and an Introduction to Reactivity. Thermodynamics and Kinetics  190 6  The Reactions of Alkenes. The Stereochemistry of Addition Reactions  235 7  The Reactions of Alkynes. An Introduction to Multistep Synthesis  288 8  Delocalized Electrons: Their Effect on Stability, pKA, and the Products of a Reaction. Aromaticity and Electronic Effects: An Introduction to the Reactions of Benzene  318 9  Substitution and Elimination Reactions  391 10  Reactions of Alcohols, Ethers, Epoxides, Amines, and Sulfur-Containing Compounds  458 11  Organometallic Compounds  508 12  Radicals  532 13  Mass Spectrometry; Infrared Spectroscopy; UV/Vis Spectroscopy  567 14  NMR Spectroscopy  620 15  Reactions of Carboxylic Acids and Carboxylic Acid Derivatives  686 16  Reactions of Aldehydes and Ketones. More Reactions of Carboxylic Acid Derivatives  739 17  Reactions at the α-Carbon  801 18  Reactions of Benzene and Substituted Benzenes  868 19  More About Amines. Reactions of Heterocyclic Compounds  924 20  The Organic Chemistry of Carbohydrates  950 21  Amino Acids, Peptides, and Proteins  986 22  Catalysis in Organic Reactions and in Enzymatic Reactions  1030 23  The Organic Chemistry of the Coenzymes, Compounds Derived from Vitamins  1063 24  The Organic Chemistry of the Metabolic Pathways  1099 25  The Organic Chemistry of Lipids  1127 26  The Chemistry of the Nucleic Acids  1155 27  Synthetic Polymers  1182 28  Pericyclic Reactions  1212

Chapitre 8 : Delocalized Electrons: Their Effect on Stability, pKA, and the Products of a Reaction. Aromaticity and Electronic Effects: An Introduction to the Reactions of Benzene   Page   Delocalized Electrons Explain Benzene's Structure  319  The Bonding in Benzene  321  Resonance Contributors and the Resonance Hybrid  322  How to Draw Resonance Contributors  323  The Predicted Stabilities of Resonance Contributors  326  Delocalization Energy is the Additional Stability Delocalized Electrons Give to a Compound  329  Delocalized Electrons Increase Stability  330  A Molecular Orbital Description of Stability  335  Delocalized Electrons Affect pKA Values  339  Electronic Effects  342  Delocalized Electrons Can Affect the Product of a Reaction  346  Reactions of Dienes  347  Thermodynamic Versus Kinetic Control  350  The Diels–Alder Reaction is a 1,4-Addition Reaction  355  Retrosynthetic Analysis of the Diels–Alder Reaction  361  Benzene is an Aromatic Compound  362  The Two Criteria for Aromaticity  363  Applying the Criteria for Aromaticity  364  A Molecular Orbital Description of Aromaticity  367  Aromatic Heterocyclic Compounds  368  How Benzene Reacts  370