Agrégation chimie Montrouge

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Titre de l'ouvrage : Stereoelectronic Effects (V. Alabugin, 2016)

Table des chapitres

 Num. Chap.  Titre du chapitre  Page 
1  Introduction  1
2  Direct Effects of Orbital Overlap on Reactivity  8
3  Beyond Orbital Overlap: Additional Factors Important for Orbital Interactions. Classifying Delocalizing Interactions  42
4  Computational and Theoretical Approaches for Studies of Stereoelectronic Effects  54
5  General Stereoelectronic Trends – Donors, Acceptors, and Chameleons  62
6  Stereoelectronic Effects with Donor and Acceptor Separated by a Single Bond Bridge: The Broad Spectrum of Orbital Contributions to Conformational Analysis  97
7  Stereoelectronic Effects with Donor and Acceptor Separated by a Vinyl Bridge  183
8  Remote Stereoelectronic Effects  214
9  Transition State Stabilization with Stereoelectronic Effects: Stereoelectronic Control of Reaction Bottlenecks  236
10  Stereoelectronic Effects in Reaction Design  257
11  Stereoelectronic Effects in Action: The Many Doors Opened by Orbital Interactions  275
12  Probing Stereoelectronic Effects with Spectroscopic Methods  322
 
 Chapitre 9 : Transition State Stabilization with Stereoelectronic Effects: Stereoelectronic Control of Reaction Bottlenecks   Page 
 Torquoselectivity  240
 Diastereoselection in nucleophilic addition to carbonyl compounds and other π-systems  243
 Electrophilic addition to enamines  245
 Hyperconjugative assistance to alkyne bending and alkyne cycloadditions  246
 Negative conjugation – donation from oxygen lone pairs to breaking bonds  248
 Remote lone pairs in radical reactions: fragmentations  251
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