| Titre |
Page |
Fichier
| Note |
| Recrystallization and solubility tests: from water and from organic solvents |
208 |
 |
- |
| Stirring and decanting: preparing biodiesel from cooking oil |
213 |
|
- |
| Simple distillation: isolation of alcohol from wine |
216 |
|
- |
| Extraction and "rotary evaporator": obtaining cloves and cinnamon oils |
218 |
|
- |
| Liquid-liquid extraction (with centrifuge): isolation of caffeine from soluble coffee |
220 |
|
- |
| Liquid-liquid extraction (with separatory funnel): separating components of a mixture |
222 |
|
- |
| Reflux, simple, and fractional distillation: ethyl acetate preparation |
227 |
|
- |
| Steam distillation and vacuum distillation: isolation of limonene from citrus peel |
230 |
|
- |
| Solid-liquid extraction (Soxhlet): sunflower oil from seeds |
232 |
|
- |
| TLC and CC chromatography: separation of the pigments from spinach leaf |
234 |
|
- |
| Alkene oxidation: preparation of adipic acid from cyclohexene |
240 |
|
- |
| Dehydration of alcohols: synthesis of cyclohexene from cyclohexanol |
242 |
|
- |
| Oxidation of alcohols: 4-chlorobenzoic acid from 4-chlorobenzyl alcohol |
244 |
|
- |
| Nucleophilic substitution reactions: synthesis of 1-bromobutane |
246 |
|
- |
| Synthesis of an ether: preparation of β-naphthyl methyl ether |
250 |
|
- |
| Aromatic electrophilic substitution of an ester: methyl benzoate nitration |
252 |
|
- |
| Electrophilic aromatic substitution (SEAr): preparation of a synthetic detergent |
254 |
|
- |
| Synthesis of azo dyes: methyl orange |
256 |
|
- |
| Auto-oxidation−reduction of aromatic aldehydes: Cannizzaro reaction |
259 |
|
- |
| Synthesis of α,β-unsaturated ketones: Claisen-Schmidt reaction |
262 |
|
- |
| Saponification reaction: preparation of soap from vegetable oil |
265 |
|
- |
| Esterification: synthesis of aspirin |
267 |
|
- |
| Difunctional compound chemoselectivity: reduction of 4-nitroacetophenone |
269 |
|
- |
| Perkin reaction: cinnamic acid synthesis |
272 |
|
- |
| Synthesis of imide: preparation of N-(p-chlorophenyl)-maleimide |
274 |
|
- |
| Condensation polymerization reaction: synthesis of nylon 6,6 |
276 |
|
- |
| Radical polymerization: producing polystyrene |
278 |
|
- |
| Multistep synthesis of a drug: paracetamol |
280 |
|
- |
| Multistep synthesis of an anesthetic: preparation of benzocaine |
283 |
|
- |
| Using protecting groups: multistep synthesis of p-nitroaniline |
286 |
|
- |
| Reductive amination: producing (±)-α-methylbenzylamine |
292 |
|
- |
| Chiral resolution: (±)-α-methylbenzylamine |
294 |
|
- |
| Stereospecific synthesis of glycols: preparation of trans-cyclohexane-1,2-diol |
297 |
|
- |
| Reactivity of carbenes: preparation of 7,7-dichlorobicyclo[4.1.0]heptane |
300 |
|
Chloroforme : à éviter |
| Regioselective halogenations: bromation of α-methylstyrene |
302 |
|
-bromation |
| Oxidative coupling of alkynes: the Glaser-Eglinton-Hay coupling |
304 |
|
- |
| Diels-Alder reactions: butadiene and maleic anhydride |
306 |
|
- |
| Wittig reaction: 4-vinylbenzoic acid synthesis |
308 |
|
- |
| Grignard reagents: synthesis of triphenylmethanol (triphenylcarbinol) |
311 |
|
- |
| Organometallic compounds: synthesis of acetylferrocene |
314 |
|
- |
| Chemoselectivity: cinnamaldehyde reduction with LiAlH4 |
317 |
|
- |
| Electrophilic aromatic substitution (SEAr): 1,4-di-tert-butylbenzene |
320 |
|
- |
| Hofmann rearrangement: synthesis of 2-aminobenzoic acid (anthranilic acid) |
323 |
|
- |
| Radical coupling: synthesis of pinacol and pinacolone |
325 |
|
- |
| Synthesis of a heterocyclic drug: n-butyl-barbituric acid |
328 |
|
- |
| Transformations of hydroxy ketone: synthesis and reactions of benzoin |
331 |
|
- |
| Enamines as reaction intermediates: producing 2-acetylcyclohexanone |
334 |
|
- |
| N-Heterocycle synthesis: producing benzotriazol |
336 |
|
- |
| Synthesis of macrocycles: preparation of calix[4]pyrrole |
338 |
|
- |
| Preparation of a sports dietary supplement: creatine synthesis |
340 |
|
- |
| Claisen condensation: synthesis of ethyl acetoacetate |
342 |
|
- |
| Terpene transformation: citral conversion in α- and β-ionone |
344 |
|
- |
| Carbohydrates: diisopropylidene derivative of glucose |
346 |
|
- |
| Preparation of a nucleoside: multistep synthesis of uridine derivative |
348 |
|
- |
| Addition of HX to alkenes: synthesis of 2-bromohexane |
372 |
|
- |
| Production of margarine: partial hydrogenation of a vegetable oil with cyclohexene and Pd(C) |
374 |
|
- |
| Isomerization of alkenes: derivatives of fumaric acid from maleic acid |
376 |
|
- |
| Nucleophilic substitution reaction: ethyl iodide from ethanol |
378 |
|
- |
| Methylketone reactivity: acetophenone oxidation with sodium hypochlorite |
380 |
|
- |
| Electrophilic aromatic substitution (SEAr): preparation of 4-methyl-3- and 4-methyl-2-nitroacetanilide from 4-methylaniline |
382 |
|
- |
| Sandmeyer reaction: 2-iodobenzoic acid synthesis |
385 |
|
- |
| Synthesis of a carbohydrate derivative: preparation of 2,3:5,6-di-O-isopropylidene-α-D-mannofuranose |
387 |
|
- |
| Free-radical halogenation: 9-bromoanthracene preparation |
389 |
|
- |
| Alkylbenzene oxidation: reactivity of alkyl groups in aromatic compounds with KMnO4 |
391 |
|
- |
| Reduction of anthraquinone: anthrone synthesis |
393 |
|
- |
| Compounds for the fragrance industry: ester synthesis |
395 |
|
- |
| Tandem transesterification-esterification: wintergreen oil from aspirin tablets |
399 |
|
- |
| Polyfunctional molecule reactivity: vanillin transformations |
401 |
|
- |
| Multistep synthesis of N-heterocycles: triphenylpyridine preparation |
404 |
|
- |
| Synthesis of five-membered heterocycles: 2,5-dimethyl-1-phenylpyrrole by Paal-Knorr reaction |
406 |
|
- |
| Oxidative cleavage of alkenes: producing adipic acid with H2O2/Na2WO4 |
418 |
|
- |
| Halogen addition to alkenes: addition of bromine to cyclohexene |
421 |
|
-brome |
| Green epoxidation: cyclohexene reaction with Oxone® |
423 |
|
- |
| Acylation of aromatic amines: obtention of acetanilide with acetic acid and Zn |
425 |
|
- |
| Friedel-Crafts alkylation: xylene reaction with 2-bromopropane catalyzed with graphite |
429 |
|
- |
| Regiospecific nitration of phenols: obtention of ortho-nitrophenol |
431 |
|
- |
| Oxidation of aromatic aldehydes: reaction of benzaldehyde with Oxone® |
433 |
|
- |
| Green synthesis of ethers: preparation of benzyl butyl ether |
435 |
|
- |
| Synthesis of an acetal in water: preparation of 5,5-bis(hydroxymethyl)-2-phenyl-1,3-dioxane |
437 |
|
- |
| Reduction of a ketone alkaline solution: cyclohexanone reaction with NaBH4 |
439 |
|
- |
| Solvent-free Baeyer-Villiger reaction: oxidation of 4-tert-butylcyclohexanone |
441 |
|
- |
| Enzymatic reduction of β-ketoesters: synthesis of chiral ethyl 3-hydroxybutanoate |
443 |
|
- |
| C--C Bond forming: Suzuki reaction |
445 |
|
- |
| C=C Bond formation in the absence of solvent: the Wittig reaction |
447 |
|
- |
| Diels-Alder in water: reaction of 9-anthracenemethanol with N-methylmaleimide |
449 |
|
- |
| Green synthesis of a p-cymene: preparation of p-cymene from limonene |
451 |
|
- |
| Oxidative coupling reaction in water: synthesis of racemic 1,1′-bi-2-naphthol |
454 |
|
- |
| Organic compounds from recycled polymer: phthalate derived from PET |
456 |
|
- |
| Crosslinked biodegradable polymers: producing slime |
459 |
|
- |
| Polymers from renewable raw materials: starch |
461 |
|
- |
| Organocatalysis: reaction of 4-nitrobenzaldehyde and dimedone |
463 |
|
- |
| Knoevenagel-Pinner reactions in water: synthesis of 7-hydroxy-3-carboxycoumarin |
466 |
|
- |
| Biginelli reaction: synthesis of tetrahydropyrimidinone |
468 |
|
- |
| Preparation of a dipyrrol derivative in water: meso-diethyl-2,2′-dipyrromethane |
472 |
|
- |
| Ionic liquid in water: one-pot 1-butyl-3-methylimidazolium derivative preparation |
474 |
|
- |
| Beckmann rearrangement: synthesis of laurolactam from cyclododecanone |
476 |
|
- |
| Fluorescent natural product: preparation of 7-hydroxy-4-methyl-2H-chromen-2-one |
479 |
|
- |
| Photochemical solid phase: [2+2] cycloaddition of cinnamic acid |
481 |
|
- |
